COPPER-Z 4/4
HELENA CHEMICAL COMPANY
6075 POPLAR, SUITE 500
MEMPHIS, TN 38119
PHONE:901-761-0050OR CHEMTREC1-800-424-9300
Effective: 11/02/95
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I. IDENTIFICATION
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Chemical Name: Formulated mixture
Chemical Family: Inorganic metal salts
Formula: Not applicable, formulated mixture.
Synonyms: None
CAS Number: See Ingredient Statement, Section III.
EPA Registry No.: 5905-486
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II. PHYSICAL DATA
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Boiling Point: >100 degrees C.
Freezing Point: <32 degrees F.
Specific Gravity: 1.265 gms/cc
Vapor Pressure: 21 mm hg
Vapor Density: Not established
Solubility in Water: 97.5%
Per Cent Volatiles: <0.5%
Evaporation Rate: Not established
Melting Point: Not applicable
Appearance & Odor: Clear black liquid, ammonia odor.
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III. INGREDIENTS
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                                              TLV (UNITS)
MATERIAL                      %                              HAZARD
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Formulated blend of copper    100.00          15 mg/m3       Skin & eye
and zinc sulfate, carboxylic                                 irritant
acids, ammonium hydroxide and
sulphonated lignins
Copper sulfate-7758-99-8
Zinc Sulfate-7733-02-0
Carboxylic acids-Trade secret
Ammonium hydroxide-1336-21-6
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IV. FIRE AND EXPLOSION HAZARD DATA
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Flash Point: Non-combustible
Autoignition Temperature: Not applicable
Flammable Limits: Not applicable
Extinguishing Media: Non-combustible liquid. Use extinguishing media for
underlying cause of fire.
Special Fire Fighting Procedures: Wear self-contained breathing apparatus
and full protective equipment. Use water spray to cool containers exposed
to heat and flame.
Unusual Fire and Explosion Hazards: Product may produce toxic fumes under
fire conditions.
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V. HEALTH HAZARD
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Carcinogenicity Information: None currently known.
Acute Effects of Overexposure
Swallowing: The acute oral LD50 (rats) = 1280 mg/kg.
Skin Absorption: The acute dermal LD50 (rats) = >2020 mg/kg.
Inhalation: The acute inhalation LC50 (rats) = >5.64 mg/L/4h.
Skin Contact: Slightly irritating to the skin. Not a skin sensitizer.
Eye Contact: Corrosive. May cause eye damage.
Chronic Effects: None currently known.
Other Health Hazards: None currently known.
Emergency and First Aid Procedures
Swallowing: Drink a large quantity of milk, egg whites, or gelatin
solution. Do not induce vomiting. Obtain medical attention immediately.
Skin: Wash skin thoroughly with soap and water. Obtain medical attention if
irritation develops.
Inhalation: Move to fresh air, obtain medical attention if irritation
develops.
Eyes: Flush eyes with water for 15 minutes, holding eyelids open. Obtain
medical attention if irritation develops.
Notes to Physician: In the event of an adverse response, treatment should
be directed toward control of the symptoms.
Probably mucosal damage may contraindicate use of gastric lavage.
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VI. REACTIVITY DATA
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Stability: Stable
Conditions to Avoid: None currently known.
Polymerization: Will not occur
Conditions to Avoid: None currently known.
Incompatibility Materials: Product may react vigorously with alkaline
materials.
Hazardous Combustion: Sulphur dioxide, oxides of carbon, and ammonia under
fire conditions.
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VII. SPILL OR LEAK PROCEDURES
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Steps to be Taken if Material is Released or Spilled: Capture product,
reuse material if uncontaminated. If contaminated, absorb material with an
absorbent such as clay or sand and place in suitable container for proper
disposal. Do not contaminate water supplies.
Waste Disposal Method: This material must be disposed of according to
Federal, state, or local procedures under the Resource Conservation and
Recovery Act.
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VIII. SPECIAL PROTECTION INFORMATION
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Respiration: Under uncontrolled conditions use NIOSH/MSHA cartridge type
respirator approved for ammonia gas.
Ventilation: Local exhaust sufficient.
Gloves: Impervious
Eyes: Splash proof goggles.
Others: Eye wash station, impervious apron and footwear.
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IX. SPECIAL PRECAUTIONS
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Precautions to be Taken in Handling and Storing
Keep out of reach of children. Do not store with food, feed, or other
material to be used or consumed by humans or animals. Do not contaminate
water supplies, lakes, streams, or ponds.
Other Precautions: None currently known.
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X. SHIPPING INFORMATION
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D.O.T. Data--Proper Shipping Name: Not regulated by DOT.
Hazard Class: None
Identification No.: None
Labels Required: None
Placarding: None
Freight Classification: Compound, fertilizer (manufactured fertilizer)
liquid, NOIBN
CHEMICAL NAME                                                EQUIVALENT R.Q.
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Zinc sulfate, CAS #7733-02-0                                1,000 lb(454 kg)
Ammonium hydroxide, CAS #1336-21-6                          1,000 lb(454 kg)
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XI. GENERAL PRODUCT INFORMATION
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National Fire Protection Association Rating:
(Rating Level: 4-Extreme 3-High 2-Moderate 1-Slight 0-Minimum)
Health: 2 Fire: 0 Reactivity: 0
S.A.R.A. Title III Hazard Classification: (Yes / No)
Immediate (Acute) Health: Y
Delayed (Chronic) Health: N
Sudden Release of Pressure: N
Fire: N
Reactive: N
HELENA Chemical believes that the data contained herein is factual.
This data is not to be taken as a warranty or representation of legal
responsibility. It is offered solely for your consideration, investigation
& verification.